Emmanuel Doelsch

List of publications


Tamrat W. Z., Rose J., Grauby O., Levard C., Doelsch E., Chaurand P. and Basile-Doelsch I. Chemical composition and molecular scale structure of nanominerals formed by precipitation of biotite weathering products. Geochimica et Cosmochimica Acta, 229, 53-64.

Le Bars M., Legros S., Levard C., Chaurand P., Tella M., Rovezzi M., Browne P., Rose J., Doelsch E. Drastic change in zinc speciation during anaerobic digestion and composting: instability of nano-sized zinc sulfide.  Environmental Science & Technology, 52, 12987-12996.

Layet C., Santaella C., Auffan M., Chevassus-Rosset C., Montes M., Levard C., Ortet P., Barakat M., Doelsch E., 2017 Phytoavailability of silver at predicted environmental concentrations: does the ionic or nanoparticulate form matter? Environmental Science: Nano,


Hettiarachchi G., Donner E., Doelsch E., 2017 Introduction to Special Section: Application of synchrotron radiation-based methods for environmental biogeochemistry. Journal of Environmental Quality., 46, 1139-1145.

Legros S., Levard C., Marcato-Romain C. E., Guiresse M., Doelsch E. Anaerobic digestion alters copper and zinc speciation. Environmental Science & Technology, 51, 10326-10334.

Layet C., Auffan M., Santaella C., Chevassus-Rosset C., Montes M., Ortet P., Barakat M., Collin B., Legros S.,  Bravin M. N., Angeletti B., Kieffer I., Proux O., Hazemann J-L., Doelsch E. Evidence that soil properties and organic coating drive the phytoavailability of cerium oxide nanoparticles. Environmental Science & Technology, 51, 9756-9764.

Guigues S., Bravin M. N., Garnier C. and Doelsch E. Does specific parameterization of WHAM improves the prediction of copper competitive binding and toxicity on plant roots? Chemosphere, 170, 225-232.

Formentini T. A., Legros S., Fernandes C. V. S., Pinheiro A., Le Bars M., Levard C., Mallmann F. J. K., da Veiga M., Doelsch E. Radical change of Zn speciation in pig slurry amended soil: key role of nano-sized sulfide particles. Environmental Pollution, 222, 495-503.

Djae T., Bravin M. N., Garnier C. and Doelsch E. Parameterizing reactive dissolved organic matter with a default value skews the prediction of copper solution speciation and ecotoxicity in soil. Environmental Toxicology and Chemistry, 36, 898-905.


Alexandre A., Balesdent J., Cazevieille P., Chevassus-Rosset C., Signoret P., Mazur J-C., Harutyunyan A., Doelsch E., Basile-Doelsch I., Miche H., Santos G. M., 2016. Direct uptake of organic carbon by grass roots and allocation in leaves and phytoliths: 13C labeling evidence. Biogeosciences Discussion, 13: 1693-1703.

Guigues S., Bravin M. N., Garnier C., Masion A., Chevassus-Rosset C., Cazevieille P. and Doelsch E., 2016.  Amino acid involvement in high-affinity copper complexation in tomato and wheat root apoplasts: spectroscopic and thermodynamic evidence. Metallomics, 8: 366-376.

Hodomihou R.N., Feder F., Masse D., Agbossou K. E., Amadji G. L., Doelsch E., 2016.  Diagnostic de contamination des agrosystèmes périurbains de Dakar par les éléments traces métalliques. Biotechnologie, Agronomie, Société et Environnement, 20, 397-407.

Tella M., Bravin M. N., Thuries L., Cazevieille P., Chevassus-Rosset C., Collin B., Chaurand P., Legros S. and Doelsch E., 2016. Increased zinc and copper availability in organic waste amended soil: evidence of distinct release mechanisms. Environmental Pollution, 212: 299-306.


Formentini T. A., Mallmann F. J. K., Pinheiro A., Fernandes C. V. S., Bender M. A., da Veiga M., Rheinheimer dos Santos D., Doelsch E., In press Copper and zinc accumulation and fractionation in a clayey Hapludox soil subject to long-term pig slurry application. Science of the Total Environment, 536: 831-839.

Hodomihou, N. R., Feder F., Doelsch E., Agbossou K. E., Amadji, G. L., Ndour-Badiane Y., Cazevieille P., Chevassus-Rosset C., Masse D., 2015. Caractérisation des risques de contamination des agrosystèmes périurbains de Dakar par les éléments traces métalliques. Agronomie Africaine, 27 (1): 69 - 82.

Ren Z-L., Tella M., Bravin M. N., Comans Rob N.J., Dai J., Garnier J-M., Sivry Y., Doelsch E., Straathof A. and Benedetti M. Effect of Dissolved Organic Matter Composition on Metal Speciation in Soil Solutions. Chemical Geology, 398: 61-69.

Feder F., Bochu V., Findeling A., Doelsch E. Repeated pig manure applications modify nitrate and chloride competition and fluxes in a Nitisol. Science of the Total Environment, 511: 238-248.

Wassenaar T., Bravin M. N., Dumoulin F. and Doelsch E., 2015. Ex-ante fate assessment of trace organic contaminants for decision making: A post-normal estimation for sludge recycling in Reunion. Journal of Environmental Management, 147: 140-151.


Romeo A., Vacchina V., Legros S. and Doelsch E., 2014. Zinc fate in animal production systems. Metallomics, 6: 1999-2009.

Guigues S., Bravin M. N., Garnier C., Masion A. and Doelsch E., 2014.Isolated cell walls exhibit cation binding properties distinct from those of plant roots. Plant and Soil, 381: 367-379. 

Collin B., Doelsch E., Keller C., Cazevieille P., Tella M., Chaurand P., Panfili F., Hazeman J-L., Meunier J.-D. Evidence of sulfur-bound reduced copper in bamboo exposed to high silicon and copper concentrations. Environmental Pollution, 187: 22-30.

Wassenaar T., Doelsch E., Feder F., Guerrin F., Paillat J.-M., Thuriès L., Saint Macary H. Returning Organic Residues to Agricultural Land (RORAL) - fuelling the Follow the Technology approach. Agricultural Systems, 124: 60-69.


Collin B., Doelsch E., Keller C., Panfili F., Meunier J.-D., 2013. Effects of silicon and copper on bamboo grown hydroponically. Environmental Science and Pollution Research, 20(9): 6482-6495.

M. Tella, Doelsch E., Letourmy P., Chataing S., Cuoq F., Bravin M.N. and Saint Macary H., 2013. Investigation of potentially toxic heavy metals in different organic wastes used to fertilize market garden crops.  Waste Management, 33: 184-192.

Legros S., Doelsch E., Feder F., Moussard G., Sansoulet J., Gaudet J.-P., Rigaud S., Basile Doelsch I., Saint Macary H. and Bottero J-Y., 2013. Fate and behaviour of Cu and Zn from pig slurry spreading in a tropical water-soil-plant system. Agriculture, Ecosystems & Environment, 164: 70-79.


Llorens I., Lahera E., Delnet W., Proux O., Braillard A., Hazemann J-L., Prat A., Testemale D., Dermigny Q., Gelebart F., Morand M., Shukla A., Bardou N., Ulrich O., Arnaud S., Berar J-F., Boudet N., Caillot B., Chaurand P., Rose J., Doelsch E., Martin P., Solari P. L. High energy resolution five-crystal spectrometer for high quality fluorescence and absorption measurements on an X-ray Absorption Spectroscopy beamlineReview of Scientific Instrument, 8: 1-9.

Levard C., Doelsch E., Basile-Doelsch I., Chaurand P., Miche H., Masion A., Rose J., Borschneck D., Bottero J.-Y., 2012. Structure and distribution of Allophanes, Imogolite and Proto-Imogolite in Volcanic Soils. Geoderma, 183-184(0): 100-108.

  Collin B., Doelsch E., Keller C., Panfili F., Meunier J.D., 2012. Distribution and variability of silicon, copper and zinc in different bamboo species. Plant and Soil, 351(1): 377-387.


Doelsch E., Basile-Doelsch I., Bottero J.-Y., Cazevieille P. Chevassus-Rosset C., Feder F., Garnier J.-M., Gaudet J.-P., Legros S., Levard C., Masion A., Moussard G., Moustier S., Rose J., Saint-Macary H., 2011 Recyclage agricole des déchets organiques dans les sols tropicaux (Ile de La Réunion) : quel impact sur les transferts d'éléments traces métalliques ? Étude et Gestion des Sols, 18(3): 175-186.

Doelsch E., Auffan M, Bottero J-Y, Chaurand P, Legros S, Levard C, Masion A, Rose J., 2011. Déchets, polluants et nanomatériaux : valorisation, dépollution, impacts environnementaux et toxicologiques. Actualité Chimique, 356-357: 91-96. 

Levard C., Masion A., Rose J., Doelsch E., Borschneck D., Olivi L., Chaurand P., Dominici C., Ziarelli F., Thill A., Maillet P., Bottero J.Y., 2011. Synthesis of Ge-imogolite: influence of the hydrolysis ratio on the structure of the nanotubes. Physical Chemistry Chemical Physics 13(32): 14516-14522.


Collin B., Doelsch E., 2010. Impact of high natural soilborne heavy metal concentrations on the mobility and phytoavailability of these elements for sugarcane. Geoderma, 44(18): 6926-6932.

Legros S., Chaurand P., Rose J., Masion A., Briois V., Ferrasse J.-H., Saint-Macary H., Bottero, J.-Y., Doelsch E., 2010. Investigation of copper speciation in pig slurry by a multi-technical approach: size fractionation, X-ray micro-spectroscopy, thermodynamic modelling and X-ray Absorption Near Edge Structure spectroscopy. Environmental Science & Technology, 44(18): 6926-6932.

Levard,C., Rose J., Thill A., Masion A., Doelsch E., Maillet P., Spalla O., Olivi L., Cognigni A., Ziarelli F., Bottero J-Y., 2010. Formation and growth mechanisms of imogolite-like aluminogermanate nanotubes. Chemistry of Materials, 22 (8): 2466-2473.

Maillet P., Levard C., Larquet E., Mariet C., Spalla O., Menguy N., Masion A., Doelsch E., Rose J., Thill A., 2010. Evidence of Double-Walled Al-Ge Imogolite-Like Nanotubes. A Cryo-TEM and SAXS Investigation. Journal of American Chemical Society, 132 (4): 1208-1209.

Doelsch E., Masion A., Moussard G., Chevassus-Rosset C., Wojciechowicz O., 2010. Impact of pig slurry and green wastes compost application on the exchangeable fractions of heavy metals of tropical soils. Geoderma, 155 (3-4): 390-400.

Legros S., Doelsch E., Masion A., Rose J., Borschneck D., Proux O., Hazemann J-L., Saint-Macary H., Bottero J.-Y., 2010. Combining size fractionation, scanning electron microscopy and X-ray absorption spectroscopy to probe Zn speciation in pig slurry. Journal of Environmental Quality, 39 (2): 531-540.


Levard C., Masion A., Rose J., Doelsch E., Borschneck D., Dominici C., Ziarelli F., Bottero J., 2009. Synthesis of Imogolite Fibers from Decimolar Concentration at Low Temperature and Ambient Pressure: A Promising Route for Inexpensive Nanotubes. Journal of American Chemical Society, 131 (47): 17080-17081.

Levard C., Doelsch E., Rose J., Masion A., Basile-Doelsch I., Proux O., Hazemann J-L., Borschneck D., Bottero J.-Y., 2009. Role of natural nanoparticles on the behaviour of Ni in andosoils of la Reunion. Geochimica et Cosmochimica Acta, 73(16): 4750-4760.

Doelsch E., Masion A., Cazevieille P. and Condom N., 2009. Spectroscopic characterization of organic matter of a soil and vinasse mixture during aerobic and anaerobic incubation. Waste Management, 29(6): 1929-1935.


Levard C., Rose J., Masion A., Doelsch E., Borschneck D., Olivi L., Dominici C., Grauby O., Woicik J.C. and Bottero J.-Y., 2008. Synthesis of Large Quantities of Single-Walled Aluminogermanate Nanotube. Journal of American Chemical Society, 130(18): 5862-5863.

Doelsch E., Moussard G. and Saint Macary H., 2008. Fractionation of tropical soilborne heavy metals-Comparison of two sequential extraction procedures. Geoderma, 143(1-2): 168-179.


Doelsch E., Deroche B. and Van de Kerchove V., 2006. Impact of sewage sludge spreading on heavy metal speciation in tropical soils (Reunion, Indian Ocean). Chemosphere, 65(2): 286-293.

Doelsch, E., Basile-Doelsch, I., Rose, J., Masion, A., Borschneck, D., Hazemann, J.L., SaintMacary, H. and Bottero, J.-Y., 2006. New Combination of EXAFS Spectroscopy and Density Fractionation for the Speciation of Chromium within an Andosol. Environmental Science & Technology, 40(24): 7602-7608.

Doelsch E., Van de Kerchove V. and Saint Macary H., 2006. Heavy metal content in soils of Reunion (Indian Ocean). Geoderma, 134(1-2): 119-134.

Doelsch E., Saint Macary H. and Van de Kerchove V., 2006. Sources of very high heavy metal content in soils of volcanic island (La Reunion). Journal of Geochemical Exploration, 88(1-3): 194-197.


Doelsch E., Masion A., Rose J., Stone W.E.E., Bottero J.-Y. and Bertsch P.M., 2003. Chemistry and structure of colloids obtained by hydrolysis of Fe(III) in the presence of SiO4 ligands. Colloids and Surfaces A: Physicochemical and Engineering Aspects., 217: 121-128.


Doelsch E., Rose J., Masion A., Bottero J.-Y., Nahon D. and Bertsch P.M., 2002. Hydrolysis of Iron(II) Chloride under Anoxic Conditions and Influence of SiO4 Ligands. Langmuir, 18(11): 4292-4299.


Masion A., Doelsch E., Rose J., Moustier S., Bottero J.-Y. and Bertsch P.M., 2001. Speciation and Crystal Chemistry of Iron(III) Chloride Hydrolyzed in the Presence of SiO4 Ligands. 3.Semi-local Scale Structure of the Aggregates. Langmuir, 17(16): 4753-4757.

Doelsch, E., Stone, W.E.E., Petit, S., Masion, A., Rose, J., Bottero, J.-Y. and Nahon, D., 2001. Speciation and crystal chemistry of  Fe(III) chloride hydrolyzed in the presence of SiO4 ligands. 2. Characterization of Si-Fe aggregates by FTIR and 29Si solid-state NMR. Langmuir, 17(5): 1399-1405.


Doelsch E., Rose J., Masion A., Bottero J.-Y., Nahon D. and Bertsch P.M., 2000. Speciation and crystal chemistry of iron (III) chloride hydrolyzed in the presence of SiO4 ligands. 1. An Fe K-edge EXAFS study. Langmuir, 16(10): 4726-4731.


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